THE SINGLE-CRYSTAL AND ION-ASSOCIATION CIRCULAR DICHROISM SPECTRA OF THE BIS(R)-2-METHYL-1,4,7-TRIAZACYCIONONANE]COBALT(III) ION
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چکیده
منابع مشابه
Signatures of counter-ion association and hydrogen bonding in vibrational circular dichroism spectra.
We study the effect of counter-ion complexation on the example of Cl(-) ions interacting with the [Co(en)(3)](3+) complex. The H-bonding of the N-H groups of the ethylenediamine (en) ligands with the Cl(-) ions may lead to giant enhancement of the VCD intensity for the N-H stretches, but may also lead to VCD sign changes in the finger print region of N-H wagging, twisting and scissoring motions...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1978
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1978.1045